In recent years, the department has expanded its analytical capacity through investment in new analytical and imaging equipment, enabling a wider range of scientific techniques to be applied to the study of the collection. This provided an important context for the project and supported the use of multiple complementary techniques, including digital microscopy, multispectral imaging, hyperspectral imaging, fibre optic reflectance spectroscopy, and XRF spectroscopy, to investigate pigment composition and condition.
The analysis revealed a number of material variations across the manuscript. In several areas, red pigments (particularly along the margins) showed signs of discolouration, with Red Lead identified as the most reactive of the inorganic reds present. Similar changes were also observed in some pink and white passages containing lead-based pigments, likely reflecting their sensitivity to environmental conditions over time.
In areas where Verdigris had been used, signs of oxidation were detected, often visible from the verso of the folios. In other passages, yellow pigments appeared to have darkened over time, consistent with known interactions between materials such as Orpiment and Lead White.
Taken together, these observations helped build a clearer picture of how different pigments behave under changing environmental conditions, while also contributing to a deeper understanding of the manuscript’s history and early painting techniques.
For me, this collaboration between departments was one of the most rewarding aspects of the project. It demonstrated how different forms of expertise (visual, technical, and scientific) can come together to deepen our understanding of historic materials and support their long-term preservation.
Preparing the workspace
As the manuscript had already been rebound, by the time the scientific analysis was carried out, examining individual folios required careful planning to ensure it could be studied safely without placing strain on its structure.
Soft supports were arranged to allow the book to open comfortably, and a bespoke cardboard-frame mount was prepared to support individual folios during analysis. This mount helped isolate the folio under investigation and reduced potential interference from the underlying pages.